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Master's Dissertation
DOI
https://doi.org/10.11606/D.85.2016.tde-07102016-080128
Document
Author
Full name
Antonio de Jesus Alves de Quina
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
São Paulo, 2016
Supervisor
Committee
Watanabe, Shigueo (President)
Chubaci, Jose Fernando Diniz
Mamani, Nilo Francisco Cano
Title in Portuguese
Estudos das Propriedades de Termoluminescência (TL), Ressonância Paramagnética (EPR) e Absorção Ótica (AO) para caracterização do mineral Monticelita
Keywords in Portuguese
Absorção Ótica
Monticelita
Olivina
silicato
termoluminescência
Abstract in Portuguese
Foram estudados as propriedades de absorção ótica, de termoluminescência e de ressonância paramagnética eletrônica do mineral natural de silicato de nome MONTICELITA do grupo Olivina, para caracterização desse mineral, cuja formula química é CaMgSiO4. A absorção ótica mostrou que há três bandas de absorção em 450 nm, 660 nm e 1050 nm. As duas primeiras bandas, a primeira no azul e a segunda no amarelo-vermelho são responsáveis pela cor verde da Monticelita. Essas duas bandas são consequência do elemento cromo contido no mineral absorver fótons do feixe universal no visível de frequências centradas em 450 nm e 660 nm. A banda em 1050 nm é devido ao Fe2+. As curvas de emissão de uma amostra de Monticelita irradiada com raios gama de doses entre 10 e 1000 Gy apresenta três picos em 150 °C , 270 °C e 370 °C . Pelo método da deconvolução e de várias taxas de aquecimento foram obtidos energia E1=1,35 eV e fator de frequência s1=4,98x1011 s-1 para o pico 270 °C e E2=1,70 eV e s2=1,88x1011 s-1 para pico 370 °C . A irradiação com raios gama de doses entre 5 kGy e 50 kGy produziram pico TL de 380 °C com intensidade TL em função da dose linear e crescente. Este resultado e importante para dosimetria da radiação de altas doses. O espectro EPR de uma amostra natural, mostrou um resultado não esperado e interessante. Além dos sinais típicos de interação hiperfina do Mn2+, um sinal avantajado de g =6,34 indica que o ferro formou moléculas de hematita, Fe2O3. Esse sinal desaparece com aquecimento acima de 800 °C de recozimento, dando origem dipolos magnéticos de Fe3+, que dá origem a um sinal típico em g =2. Esta descrição mostra bem a caracterização do mineral Monticelita.
Title in English
Study of the Properties Thermoluminescence (TL), Electron Paramagnetic Resonance (EPR) and Optical Absorption for characterization of mineral Montecillite
Keywords in English
Monticellite
Olivine
Optical Absorption
silicate
thermoluminescence
Abstract in English
The properties of optical absorption, thermoluminescence and electron paramagnetic resonance of natural silicate mineral named MONTICELLITE belonging to Olivine group have been investigate in order to characterize this mineral of chemical formula CaMgSiO4. The optical absorption spectrum has shown that there are three bands in visible and near infrared. They occur at 450, 660 and 1050 nm. The two first absorption bands, first one around blue and second one around yellow-red are responsible for green colour of mineral. It was shown that these two absorption bands are due to absorption by chromium contained in the material of 450 nm photon and 660 nm photon from incident beam in the spectrophotometer causing excitation from fundamental to two excited states. 1050 nm band is due to Fe2+. Glow curves of Monticellite sample irradiated with γ-rays have shown TL peaks at 150, 270 e 370 °C. Using deconvolution method and various heating rates method following activation energy and frequency factor values for 270 °C peak, E1=1.35 eV and s1=4,98x1011 s-1 and for 370 °C peak E2=1.70 eV and s2=1,88x1011 s-1. Irradiation with y-rays with dose varying from 5 to 50 kGy a linear TL vs dose curve was obtained. This result shows that Monticellite Mineral can be used for high dose radiation dosimetry. The EPR spectrum of the natural sample presented an unexpected and interesting result. Besides a typical six lines due to hyperfine interaction in Mn2+ ion, a large signal with g =6,34 indicate an aggregate of hematite (Fe2O3). This signal changes into Fe3+ signal with g =2, under annealing at high temperatures of 800 to 1100 °C. Altogether these results characterize sufficiently enough the mineral Monticellite.
 
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2016QuinaEstudos.pdf (5.72 Mbytes)
Publishing Date
2016-12-15
 
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